Joe,
There's absolutely nothing wrong with calculating segment lengths this way: (D x Pi)/ # of segs; especially if you are using at least 8 segments. The key to having enough wall thickness to play with, is what's referred to as "padding". That's the cushion you create by pretending that your finished wall thickness is going to be thicker than you actually desire. In George's drawing, you will notice that he has drawn his segment widths (inside of vessel to outside), much thicker than needed. This "padding" allows more flexibility during the actual shaping of the vessel. It also waste more wood, but the little bit of wasted wood is nothing compared to your wasted time if you run out of material in order to create the desired shape.
Have Fun,
Malcolm